Recent and original results in the Southern Ocean on mercury speciation and cadmium isotopes

AU_cruise_lowFor the first time detailed mercury (Hg) speciation was determined along an Australia-Antarctic section (Cossa, et al., 2011) and cadmium (Cd) isotopes along a South Africa-Antarctic section (Abouchami W., et al., 2011). Both were acquired along two IPY-GEOTRACES sections: SR3 CASO-GEOTRACES (GIPY6) and ZERO&DRAKE (GIPY5) respectively.

Hg species distribution suggests distinct features in the Southern ocean Hg cycle: (i) a net atmospheric Hg deposition on surface water near the ice edge, (ii) Hg enrichment in brines during sea-ice formation and (iii) a methylmercury maximum close to Antarctica, far from anthropogenic Hg emissions (Figure 1).

Cd isotope ratios and concentrations are distributed into two distinct Cd isoscapes, delimiting two biogeochemical provinces the Antarctic Circumpolar Current (ACC) and Weddell Gyre (Figure 2). A doubling of the isotope effect due to biological consumption of Cd is observed during water transport from the Weddell Sea into the ACC. The increase in the magnitude of Cd isotope fractionation, as a result of enhanced phytoplankton biomass and altered species composition in the Southern Ocean, demonstrates that Cd isotopes could potentially serve as a useful measure of biological productivity.

cossa

Figure 1. Methylated mercury species (MeHgT) distribution along the SR3 CASO–GEOTRACES transect in the Southern Ocean. Source: Author’s manuscript, definitive authenticated version published in “Geochimica et Cosmochimica Acta“.

 

Abouchami

Figure 2. (Left) Latitudinal variations in seawater Cd isotope composition, expressed as ε112/ 110Cd (solid symbol) and Cd concentration (open symbol) along Zero Meridian.  (Right) Co-variations between ε112/110Cd and [Cd] (nmol kg−1) in Southern Ocean surface waters. Source: Earth and Planetary Science Letters

 

References:

Abouchami W., Galer S.J.G., de Baar H.J.W., et al. (2011), Modulation of the Southern Ocean cadmium isotope signature by ocean circulation and primary productivity, Earth and Planetary Science Letters, 305(1-2) DOI: 10.1016/j.epsl.2011.02.044

Cossa, D., Heimbürger, L.-E., Lannuzel, D., Rintoul, S.R., Butler, E.C.V., Bowie, A.R., Averty, B., Watson, R.J., Remenyi, T., (2011), Mercury in the Southern Ocean, Geochimica et Cosmochimica Acta, 75(14): 4037-4052 DOI: 10.1016/j.gca.2011.05.001

Latest highlights

Science Highlights

Terrestrial iron inputs and reverse weathering in the Amazon mouth

Understanding the key processes that condition the net input of chemical species to the ocean is an important challenge…

01.02.2023

Science Highlights

Tracing dust deposition with aluminium and silicate at a resolution never reached before

Benaltabet and his colleagues propose a study of the dissolved aluminium and silicate fate in the Gulf of Aqaba (Red Sea).

24.01.2023

Science Highlights

Actinium-227 distribution traces at least three processes in the North Atlantic Ocean

Le Roy and colleagues report an oceanic section of Actinium-227 in the North Atlantic Ocean.

23.01.2023

Science Highlights

Do you want to know more about iron and its isotopes? This review is for you!

Authors present a comprehensive review of iron and iron isotope sources, internal cycling, and sinks in the ocean.

17.01.2023

Rechercher